Streibel Lab
Thermal Analysis And Photoionization Mass Spectrometry
TA-PIMS is involved in real-time mass spectrometric detection of trace organic components in pyrolysis and combustion gases, thermal behavior and characterization of fossil and biogenic energy sources, and organic compounds of particulate matter.
About our research
Thermal processes such as combustion and pyrolysis are among the most important technical processes with numerous applications for energy generation, engine operation and the manufacture of chemical products. As a negative side effect of these processes, the formation of organic trace substances, inorganic compounds and particulate matter (PM) occurs. Therefore, a better understanding of the mechanisms that occur at the molecular level during the course of a thermal process is of great importance for prevention and remediation measures as well as for optimization strategies. In addition, combustion and pyrolysis processes exhibit highly dynamic behavior, leading to rapid changes in concentration profiles in the reaction zone as well as in the exhaust or pyrolysis gases. Therefore, analytical methods that provide rapid detection capabilities are required. Photoionization mass spectrometry with time-of-flight mass analyzers (PI-TOFMS) is one such viable tool for characterizing thermal processes. PI-TOFMS enables the rapid generation of complete mass spectra with sub-second time resolutions. It is also among the soft ionization mechanisms in mass spectrometry that significantly minimize fragmentation. This proves advantageous when considering the large number of different trace organic compounds that may be present in exhaust gases and avoids overlapping fragment ions.
Publications
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Oeder, S. ; Sippula, O. ; Streibel, T. ; Paur, H. ; Muelhopt, S. ; Arteaga-Salas, J.M. ; Harndorf, H. ; Zimmermann, R. ; Schmidt-Weber, C.B. ; Buters, J.T.M.
Immunological effects of particles and gases from ship diesel emissions in human bronchial epithelial cells.Lau, K. ; Junk, R. ; Klingbeil, S. ; Schümann, U. ; Streibel, T.
Analysis of internal common rail injector deposits via thermodesorption photon ionization time of flight mass spectrometry.Diab, J. ; Streibel, T. ; Cavalli, F. ; Lee, S.C. ; Saathoff, H. ; Mamakos, A. ; Chow, J.C. ; Chen, L.W.A. ; Watson, J.G. ; Sippula, O. ; Zimmermann, R.
Hyphenation of a EC / OC thermal-optical carbon analyzer to photo-ionization time-of-flight mass spectrometry: An off-line aerosol mass spectrometric approach for characterization of primary and secondary particulate matter.Otto, S. ; Streibel, T. ; Erdmann, S. ; Klingbeil, S. ; Schulz-Bull, D. ; Zimmermann, R.
Pyrolysis-gas chromatography-mass spectrometry with electron-ionization or resonance-enhanced-multi-photon-ionization for characterization of polycyclic aromatic hydrocarbons in the Baltic Sea.Müller, L. ; Jakobi, G. ; Czech, H. ; Stengel, B. ; Orasche, J. ; Arteaga-Salas, J.M. ; Karg, E.W. ; Elsasser, M. ; Sippula, O. ; Streibel, T. ; Slowik, J.G. ; Prevot, A.S.H. ; Jokiniemi, J. ; Rabe, R. ; Harndorf, H. ; Michalke, B. ; Schnelle-Kreis, J. ; Zimmermann, R.
Characteristics and temporal evolution of particulate emissions from a ship diesel engine.Reda, A. ; Czech, H. ; Schnelle-Kreis, J. ; Sippula, O. ; Orasche, J. ; Wefers, B. ; Abbaszade, G. ; Arteaga-Salas, J.M. ; Kortelainen, M. ; Tissari, J. ; Jokiniemi, J. ; Streibel, T. ; Zimmermann, R.
Analysis of gas-phase carbonyl compounds in emissions from modern wood combustion appliances: Influence of wood type and combustion appliance.Oeder, S. ; Kanashova, T. ; Sippula, O. ; Sapcariu, S.C. ; Streibel, T. ; Arteaga-Salas, J.M. ; Passig, J. ; Dilger, M. ; Paur, H.R. ; Schläger, C. ; Mülhopt, S. ; Diabaté, S. ; Weiss, C. ; Stengel, B. ; Rabe, R. ; Harndorf, H. ; Torvela, T. ; Jokiniemi, J.K. ; Hirvonen, M.R. ; Schmidt-Weber, C.B. ; Traidl-Hoffmann, C. ; BéruBé, K.A. ; Wlodarczyk, A.J. ; Prytherch, Z. ; Michalke, B. ; Krebs, T. ; Prévôt, A.S. ; Kelbg, M. ; Tiggesbäumker, J. ; Karg, E.W. ; Jakobi, G. ; Scholtes, S. ; Schnelle-Kreis, J. ; Lintelmann, J. ; Matuschek, G. ; Sklorz, M. ; Klingbeil, S. ; Orasche, J. ; Richthammer, P. ; Müller, L. ; Elsasser, M. ; Reda, A. ; Gröger, T.M. ; Wefers, B. ; Schwemer, T. ; Czech, H. ; Rüger, C.P. ; Abbaszade, G. ; Radischat, C. ; Hiller, K. ; Buters, J.T.M. ; Dittmar, G. ; Zimmermann, R.
Particulate matter from both heavy fuel oil and diesel fuel shipping emissions show strong biological effects on human lung cells at realistic and comparable in vitro exposure conditions.Reda, A. ; Schnelle-Kreis, J. ; Orasche, J. ; Abbaszade, G. ; Lintelmann, J. ; Arteaga-Salas, J.M. ; Stengel, B. ; Rabe, R. ; Harndorf, H. ; Sippula, O. ; Streibel, T. ; Zimmermann, R.
Corrigendum to "Gas phase carbonyl compounds in ship emissions: Differences between diesel fuel and heavy fuel oil operation".Kleeblatt, J. ; Stengel, B. ; Radischat, C. ; Passig, J. ; Streibel, T. ; Sippula, O. ; Rabe, R. ; Harndorf, H. ; Zimmermann, R.
Needle trap sampling thermal-desorption resonance enhanced multiphoton ionization time-of-flight mass spectrometry for analysis of marine diesel engine exhaust.Reda, A. ; Schnelle-Kreis, J. ; Orasche, J. ; Abbaszade, G. ; Lintelmann, J. ; Arteaga-Salas, J.M. ; Stengel, B. ; Rabe, R. ; Harndorf, H. ; Sippula, O. ; Streibel, T. ; Zimmermann, R.
Corrigendum: Gas phase carbonyl compounds in ship emissions: Differences between diesel fuel and heavy fuel oil operation.Kanashova, T. ; Popp, O. ; Orasche, J. ; Karg, E.W. ; Harndorf, H. ; Stengel, B. ; Sklorz, M. ; Streibel, T. ; Zimmermann, R. ; Dittmar, G.A.G.
Differential proteomic analysis of mouse macrophages exposed to adsorbate-loaded heavy fuel oil derived combustion particles using an automated sample-preparation workflow.Radischat, C. ; Sippula, O. ; Stengel, B. ; Klingbeil, S. ; Sklorz, M. ; Rabe, R. ; Streibel, T. ; Harndorf, H. ; Zimmermann, R.
Real-time analysis of organic compounds in ship engine aerosol emissions using resonance-enhanced multiphoton ionisation and proton transfer mass spectrometry.Zimmermann, R. ; Hertz-Schünemann, R. ; Ehlert, S. ; Liu, C. ; McAdam, K. ; Baker, R. ; Streibel, T.
Highly time-resolved imaging of combustion and pyrolysis product concentrations in solid fuel combustion: NO formation in a burning cigarette.Hertz-Schünemann, R. ; Ehlert, S. ; Streibel, T. ; Liu, C. ; McAdam, K. ; Baker, R.R. ; Zimmermann, R.
High-resolution time and spatial imaging of tobacco and its pyrolysis products during a cigarette puff by microprobe sampling photoionisation mass spectrometry.Otto, S. ; Streibel, T. ; Erdmann, S. ; Sklorz, M. ; Schulz-Bull, D. ; Zimmermann, R.
Application of pyrolysis-mass spectrometry and pyrolysis-gas chromatography-mass spectrometry with electron-ionization or resonance-enhanced-multi-photon ionization for characterization of crude oils.Streibel, T. ; Mühlberger, F. ; Geißler, R. ; Saraji-Bozorgzad, M.R. ; Adam, T. ; Zimmermann, R.
Influence of sulphur addition on emissions of polycyclic aromatic hydrocarbons during biomass combustion.Contact
