Fluorene scientific molecular model, 3D rendering

Molecular Composition of Individual Atmospheric Particles

Toxic organic trace compounds e.g. polycyclic aromatic hydrocarbons (PAH) from industry, heating, vehicles or wildfires travel ‘on board’ of fine particles in the atmosphere. Their origin, distribution and degradation are a crucial factor for health effects from air pollution. As an example, PAHs can by equally distributed at low concentrations across many particles, or they might be concentrated on few particles, overcoming the lung’s cellular defense and leading to local inflammation – a starting point for serious health effects that are associated with asthma, cardiovascular diseases or cancer.

We developed a new type of mass spectrometer that can detect the fingerprints of PAHs on individual airborne particles in the sub-µm range – along with the particle’s inorganic composition and in real time. Thus, we can explore the detailed distribution, transport pathways and carriers of PAHs in the atmosphere for the first time, paving a route towards sophisticated environmental monitoring for human health.

The research is funded by the Helmholtz International Lab aeroHEALTH, the CRC 1477 ‘Limati’, and the German research foundation Grant ZI 764/6-1.

Co-workers: Dr. Julian Schade, Ellen Iva Rosewig, Paul Haubenwallner

Publications

2022 Atmos. Chem. Phys. 22 , 1495–1514

J. Passig, J. Schade, R. Irsig, T. Kröger-Badge, H. Czech, T. Adam, H. Fallgren, J. Moldanova, M. Sklorz, T. Streibel and R. Zimmermann

Single-particle characterization of polycyclic aromatic hydrocarbons in background air in northern Europe
2019 Anal. Chem. 91, 10282–10288

Schade, J., Passig, J., Irsig, R., Ehlert, S., Sklorz, M., Adam, T., Li, C., Rudich, Y., and Zimmermann, R.

Spatially Shaped Laser Pulses for the Simultaneous Detection of Polycyclic Aromatic Hydrocarbons as well as Positive and Negative Inorganic Ions in Single Particle Mass Spectrometry
2019 Atmos. Chem. Phys. 19, 139–163

Li, C., He, Q., Schade, J., Passig, J., Zimmermann, R., Meidan, D., Laskin, A., and Rudich, Y.

Dynamic changes in optical and chemical properties of tar ball aerosols by atmospheric photochemical aging
2017 Anal. Chem., 89, 6341–6345

Passig, J., Schade, J., Oster, M., Fuchs, M., Ehlert, S., Jäger, C., Sklorz, M., and Zimmermann, R.

Aerosol Mass Spectrometer for Simultaneous Detection of Polyaromatic Hydrocarbons and Inorganic Components from Individual Particles